Ethyl benzimidate hydrochloride, 97%, Thermo Scientific Chemicals

Description

Ethyl benzimidate hydrochloride is used in the preparation of (4R)-ethyl 2-phenyl-4,5-dihydrothiazole-4-carboxylate by reacting with (R)-ethyl cysteine hydrochloride. It also reacts with D-penicillamine methyl ester hydrochloride and triethylamine to prepare methyl-5,5- dimethyl-2-phenyl-2-thiazoline-4-carboxylate. Further, it is used as an intermediate for organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethyl benzimidate hydrochloride is used in the preparation of (4R)-ethyl 2-phenyl-4,5-dihydrothiazole-4-carboxylate by reacting with (R)-ethyl cysteine hydrochloride. It also reacts with D-penicillamine methyl ester hydrochloride and triethylamine to prepare methyl-5,5- dimethyl-2-phenyl-2-thiazoline-4-carboxylate. Further, it is used as an intermediate for organic synthesis.

Solubility
Soluble in water.

Notes
Incompatible with strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 5333-86-8
• Molecular Formula: C9H12ClNO
• Molecular Weight (g/mol): 185.65
• MDL Number: MFCD00043246
• InChI Key: MODZVIMSNXSQIH-UHFFFAOYSA-N
• Synonym: ethyl benzimidate hydrochloride, benzenecarboximidic acid, ethyl ester, hydrochloride, ethyl benzenecarboximidate hydrochloride, benzimidic acid ethyl ester hcl, ethylbenzimidate hydrochloride, ethyl benzimidate hcl, ethyl benzylimidate hydrochloride, ethyl iminobenzoate hydrochloride, benzimido ethyl ether hydrochloride, benzimidoyl ethyl ether hydrochloride
• PubChem CID: 79249
• IUPAC Name: ethyl benzenecarboximidate;hydrochloride
• SMILES: [H+].[Cl-].CCOC(=N)C1=CC=CC=C1

• Melting Point: 115°C to 117°C
• Quantity: 50 g
• Beilstein: 3697589
• Sensitivity: Hygroscopic
• Solubility Information: Soluble in water.
• Formula Weight: 185.65
• Percent Purity: 97%
• Chemical Name or Material: Ethyl benzimidate hydrochloride

Safety and Handling

Hazard Category	H315-H319-H335
Hazard Statement	GHS H Statement H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statement	P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
EINECSNumber	226-248-1
TSCA	Yes
Recommended Storage	Store under Nitrogen

SDS

RUO – Research Use Only